Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N(2) complexes.
نویسندگان
چکیده
Catalytic dehydrogenation of R(2)NHBH(3) (R = Me, H) promoted by a family of bis(cyclopentadienyl)titanium and bis(indenyl)zirconium compounds is reported; structure-reactivity relationships as a function of cyclopentadienyl and indenyl substituents have been examined.
منابع مشابه
Cyclisation of α,ω-dienes promoted by bis(indenyl)zirconium sandwich and ansa-titanocene dinitrogen complexes.
Metallation of a variety of α,ω-dienes has been explored with an η(9),η(5)-bis(indenyl)zirconium sandwich compound and an ansa-titanocene dinitrogen complex. The η(9),η(5)-bis(indenyl)zirconium sandwich compound, (η(9)-C(9)H(5)-1,3-Pr(2))(η(5)-C(9)H(5)-1,3-(i)Pr(2))Zr, served as an isolable source of Negishi's reagent and readily formed a kinetic mixture of cis and trans diastereomers of the co...
متن کاملTitanium hydroamination catalysts bearing a 2-aminopyrrolinato spectator ligand: monitoring the individual reaction steps.
A series of new titanium half sandwich complexes, containing a 2-aminopyrrolinato ligand {N(Xyl)N}(-) as the ancillary ligand, have been prepared and are shown to be pre-catalysts for the hydroamination of alkynes. The coordination of {N(Xyl)N}(-) to titanium was achieved by reaction of [Cp*TiMe(3)] with the protioligand N(Xyl)NH giving [Cp*Ti(N(Xyl)N)(Me)(2)] (). Upon reaction of complex with ...
متن کاملUnexpected neutral aza-macrocycle complexes of sodium.
Highly unusual Na(+) complexes with neutral tri- and tetra-amines are isolable in good yield from the reaction of NaBAr(F) with the amine in organic media. Structural characterisation reveals primary Na-N bonding, including an unusual sandwich cation [Na(Me3tacn)2](+), derived from homoleptic N6-coordination via two Me3-tacn ligands, and the distorted 5-coordinate [Na(thf)(Me4cyclam)](+).
متن کاملDiamido Complexes of Titanium and Zirconium as Catalyst Precursors for Ethylene Polymerization
A series of 8 new complexes of titanium and zirconium with diamido ligands bearing an ethylene and propylene bridge between the two amido groups were synthesized and tested for ethylene polymerization. Titanium complexes bearing an ethylene bridge between the two amido groups showed higher activities than the derivatives with a propylene bridge. In the case of the zirconium complexes, the p...
متن کاملComparison of Compressive Properties Between Va-cuum Infusion and Hand Lay-Up Method Toward Bal-sa Core Sandwich Composites
The aim of this work is to evaluate the influence of fabrication methods on the com-pressive properties of sandwich composites using both experimental work and numerical simulations. Two types of sandwich composites with E-glass/Kevlar/polyester resin facings and End-grain balsa wood as core have been produced by vacuum infusion processing (VIP) and hand-lay up (HL) method. Compression tests on...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 31 شماره
صفحات -
تاریخ انتشار 2007